8(3)04

Nauka innov. 2012, 8(3):23–31
https://doi.org/10.15407/scin8.03.023

V. Granchak1, V. Sysyuk2, V. Grishchenko2, P. Davyskyba2, A. Bubnova2, V. Majik3, L. Yasynska3
1L. V. Pisarzhevskii Institute of the Physical Chemistry  NAS of Ukraine, Kyiv
2Institute of Macromolecular Chemistry NAS of Ukraine, Kyiv
3About Ukrainian Academy of Printing, Lviv

 

Development and Modification of Photopolymerized Adhesives for Technological Processes of Framed Print Production

Section: Scientific and Technical Innovative Projects of National Academy of Sciences of Ukraine
Language: Ukrainian
Abstract: To improve physical and chemical, mechanical and adhesive properties of polymerizable compositions the directions of their modification were defined. A photosensitive composite material based on oligouretanacrylate aliphatic nature, oligoetheracrylate, photoinitiator system was developed. To increase the rate of coating curing the synthesis of oligomeric modifiers was conducted. The relationship between the kinetic parameters of photopolymerization and properties of the polymer coatings was determined, the directions of regulation of their functionality when interacting with different oligomeric modifiers to improve lightsensitivity and adhesion strength were defined. A pilot batch of photopolymer adhesive was produced with the next material testing at the manufacture.
Key words: photo adhesive, composite material, photopolymerization, modifier, photoinitiator, actinity, kinetics, synthesis, finishing, embossing.

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