Home /Archive /2016, Volume 12 /12(5) /Self-Sustained Flameless Heat Generator Based on Catalytic Oxidation of Methane or Propane-Butane Mixture for Various Object Heating Including Field Heating

Self-Sustained Flameless Heat Generator Based on Catalytic Oxidation of Methane or Propane-Butane Mixture for Various Object Heating Including Field Heating

TitleSelf-Sustained Flameless Heat Generator Based on Catalytic Oxidation of Methane or Propane-Butane Mixture for Various Object Heating Including Field Heating
Publication TypeJournal Article
Year of Publication2016
AuthorsStrizhak, PYe., Solovyov, SO, Trypolsky, AI, Kirienko, PI, Stoliarchuk, IL
Short TitleNauka innov.
DOI10.15407/scin12.05.032
Volume12
Issue5
SectionGeneral Questions of Modern Research and Innovation Policy
Pagination32-46
LanguageUkrainian
Abstract
An effective catalyst based on ceramic block support with honeycomb structure made of synthetic cordierite with low coefficient of temperature linear expansion has been developed. Flameless heat generator based on oxidation of methane or propane-butane mixture has been designed. Laboratory and bench testing revealed that the effectiveness of the generators is identical to foreign analogues. The production of self-sustained flameless heat catalytic generators and the catalysts have been adjusted.
Keywordscatalyst for flameless methane or propane-butane mixture oxidation, catalytic heat generator, cordierite, honeycomb structure cells
References

1. Pakharukova V.P., Moroz E.M., Zyuzin D.A., Zaikovskii V.I., Tuzikov F.V., Kosmambetova G.R., Strizhak P.E. Structure characterization of nanocrystalline yttria- stabilized zirconia powders prepared via microwave-assis ted synthesis. J. Phys. Chem. C., 2012, 116(17): 9762-9768. https://doi.org/10.1021/jp205136f
2. Patent WO1995031675 A1 World International Pro per ty Organization, PCT /GB1995/001054. Catalytic com bustion. Cox Julian P., Jenkins John W., declar. 10.05.1995, publ. 23.11.1995.
3. Patent of Russian Federation 2086298, B01J23/70, B01J23/34, B01J23/70, B01J101/00. The catalyst for the flameless combustion of natural gas. Ismagilov Z.R., Prokudina N.A., Sazonov V.A., declar. 20.02.1995, publ. 10.08.1997 [Russian].
4. Patent CN1955150 A Сhina, 200510116710. Manganese deoxidier and its preparation method and application. Lv Shunfeng Qin., declar. 02.05.2005, publ. 28.10.2005.
5. Patent WO2008145181 A1 World International Property Organization, PCT/EP2007/055186. Activated base metal catalysts. Schwarz M., Laporte S., Goettlinger M., Berweiler M., declar. 29.05.2007, publ. 04.12.2008.
6. Patent CN101947457 A Сhina, 201010268086. Ven ti lation air methane combustion catalyst and preparation method thereof. Yaozhuang C., Jian Z., Jiong L., Heng Z., Lei M., Jumei L., declar. 31.08.2010, publ. 19.01.2011.
7. Patent WO2014025274 A1 World International Property Organization, PCT/PL2013/000102, Multicomponent oxide catalyst for low-temperature oxidation of methane and the method for preparation thereof. Sojka Z., Stelam chowski P., Kotarba A., Kaczmarczyk J., Adamski A., declar. 07.08.2012, publ. 13.02.2014.
8. Gélin P, Primet M. Сomplete oxidation of methane at low temperature over noble metal based catalysts: a review. Applied Catalysis B: Environmental. 2002. Vol. 39. P. 1-37. https://doi.org/10.1016/S0926-3373(02)00076-0
9. Persson K., Thevenin P.O., Jansson K., Petersson L., Jaras S., Agrell J. Preparation of alumina-supported pal la dium catalysts for complete oxidation of methane. Applied Catalysis A: General. 2003. Vol. 249. P. 165-174. https://doi.org/10.1016/S0926-860X(03)00193-5
10. Ismagilov Z.R., Kerzhentsev M.A., Yashkina S.A., Shikin N.V. Catalysts for effective fuel combustion. Russian nanotechnologies. 2009. 4(11-12): 32-35 [Russian].
11. Strizhak P.E., Trypolskyi A.I., Kosmambetova G.R., Di denko O.Z., Gurnyk T.N. Geometric and Electronic Approaches to Size Effects in Heterogeneous Catalysis. Kinetika i Kataliz. 2011. 52(1): 131-142 [Russian]. https://doi.org/10.1134/S0023158411010186
12. Kosmambetova G.R., Moroz E.М., Guralsky A.V., Pa kharukova V.P., Boronin A.I., Ivaschenko T.S., Gritsenko V.I., Strizhak P.E. Low temperature hydrogen purification from CO for fuel cell application over copper-ceria ca talysts supported on different oxides. International Journal of Hydrogen Energy. 2011. 36(1): 1271-1275. https://doi.org/10.1016/j.ijhydene.2010.06.126
13. Kosmambetova G.R., Kriventsov V.V., Moroz E.M., Pakharukova V.P., Strizhak P.E., Zyuzin D.A. The state of the components in copper-cerium catalysts supported on different oxides. Nuclear Instruments and Methods in Physics Research Section A: Accelerators, Spectro meters, Detectors and Associated Equipment. 2009. 603(1-2): 191-193. https://doi.org/10.1016/j.nima.2009.03.002
14. Stryzhak P.E., Dolgih L.Yu., Kosmambetova G.R. New catalysts for hydrogen production and purification. Kyiv: KIM, 2010. P. 38-56 [Ukrainian].
15. Arai H., Fukuzava H. Research and development on hightemperature catalytic combustion. Catal. Today. 1995. 26(3-4): 217-221. https://doi.org/10.1016/0920-5861(95)00142-8
16. Zwinkels M.F., Jaras S.J., Menon P.J, Griffin T.A. Ca talytic materials for high-temperature combustion. Catal. Rev. Sci. Eng. 1993. 35(3): 319-358. https://doi.org/10.1080/01614949308013910
17. Cybulski A. Moulijn J.A. Structure catalysts and reaction. The present and the future of structured catalysts: an overview. New York, Taylor & Francis Group, LLC, 2006. P. 1-19. https://doi.org/10.1201/9781420028003.ch1
18. Popovich A.N., Soloviev G.I., Suvorin A.V. Research carriers on the basis of mineral fibers for catalysts catalyticstable combustion of hydrocarbons. Interdisciplinary Institute «Science and Education» 2014. No. 5. P. 91-94 [Russian].
19. Klimash A.A. Development of preparation methods, the research activity of metal foil and ceramic honeycomb catalysts in the deep oxidation of methane. Klimash A.A., Lavka S.V., Soloviev G.I. Strategy of Quality In Industry and Education. 2011. V. 3. P. 114-116 [Russian].
20. Yung M.M., Holmgreen E.M., Ozkan U.S. Low-temperature Oxidation of Carbon Monoxide on Co/ZrO2. Catal. Let. 2007. 118(3-4): 180-186. https://doi.org/10.1007/s10562-007-9216-4
21. Kolli T., Huuhtanen M., Hallikainen A., Kallinen K. The Effect of Sulphur on the Activity of Pd/Al2 O3 , Pd/CeO2 and Pd/ZrO2 Diesel Exhaust Gas Catalysts. Catal. Let. 2009. V. 127. P. 49-54. https://doi.org/10.1007/s10562-008-9651-x
22. Matsouka V., Konsolakis M., Yentekakis I.V., Papa vasiliou A., Tsetsekou A., Boukos N. Thermal aging be ha-vior of Pt-only TWC converters under simulated ex haust con ditions: effect of rare earths (CeO2, La2 O3 ) and alkali (Na) modifiers. Topics in Catalysis. 2011. 54(16): 1124-1134.

https://doi.org/10.1007/s11244-011-9734-6
23. Cassinelli W.H., Feio L.S.F., Araújo J.C.S., Hori C.E., Noronha F.B., Marques C.M.P., Bueno J.M.C. Effect of CeO2 and La2 O3 on the activity of CeO2 -La2 O3 /Al2 O3 - supported Pd catalysts for steam reforming of methane. Catal. Let. 2008. 120(1): 86-94. https://doi.org/10.1007/s10562-007-9253-z