9(3)01
Nauka innov. 2013, 9(3):5-12
https://doi.org/10.15407/scin9.03.005
L.P. Gal’chinetskii1, B.V. Grinyov1, A.Y. Dulfan2
1 Institute for Scintillation Materials, NAS of Ukraine, Kharkiv
2 National Technical University "KPI", Kharkiv
Interaction of Reactor Materials with Water Vapor and Oxygen
Section: Scientific Basis of Innovation Activity
Language: Russian
Abstract: Thermodynamics of the interaction of reactor materials (zirconium, iron, graphite) with water vapor has been analyzed. Taking into account kinetic factors it was shown that participation of oxygen in these processes leads to exothermic nature and sharp increase in the intensity of reactions, the products of which are explosive gases, firstly hydrogen. To reduce the rate of reactions with hydrogen release, reactor heating, and prevent the danger of explosive mixtures of hydrogen and oxygen, it is offered to blow the surface of reactor interaction elements containing water vapor and oxygen by nitrogen gas.
Key words: zirconium, iron, graphite, the reaction with water vapor, hydrogen, oxygen, nitrogen.
Full Text (PDF)
1. Avarija na AJeS Fukusima - ru.wikipedia.org/wiki/ Avarija_na_AJeS_Fukusima-1 [in Russian].
2. Sobytija na AJeS Fukusima-1.fukusima-1.ru/ [in Russian].
3. S.A. Kabakchi, G.P. Bulgakova. Radiacionnaja himija v jadernom toplivnom cikle. NIFHI im. L.Ja. Karpova, RHTU im. D.I. Mendeleeva, 1997, gl. 9, http:.www. chemnet.ru/rus/teaching/kabakchi/welcome.html [in Russian].
4. Fizicheskaja himija. Teoreticheskoe i prakticheskoe rukovodstvo. Pod red. B.P. Nikol'skogo. Moskva: Himija, 1987. Izd. 2-e. 374 s. [in Russian].
5. Karapet'janc M.H. Himicheskaja termodinamika. Moskva: Himija, 1975. Izd. 3-e. 584 s. [in Russian].
6. Bazy dannyh. Termicheskie konstanty veshhestv. MGU im. M. V. Lomonosova. http:.www.chem.msu.ru/cgibin/tkv.pl?show=welcome.html [in Russian].
7. Kratkaja himicheskaja jenciklopedija. Pod red. I.L. Knunjanc i dr. Moskva: Sov. jencikl., 1967. T. 5. 1184 stb. [in Russian]
8. B.A. Kalin i dr. Vlijanie strukturno-fazovogo sosto janija oksidnyh pljonok na korrozionnuju stojkost' splavov cirkonija. Trudy XVIII Mezhdunarodnoj konferencii po fizike radiacionnyh javlenij i radiacionnomu materialovedeniju, 8-13 sentjabrja 2008 g., Alushta, Krym. S. 131-132 [in Russian].
9. Kratkaja himicheskaja jenciklopedija. Pod red. I.L. Knunjanc i dr. Moskva: Sov. jencikl., 1963. T. 3. 1112 stb. [in Russian].
10. Korjakin Ju.V., Angelov I.I. Chistye himicheskie veshhestva. Rukovodstvo po prigotovleniju neorganicheskih reaktivov i preparatov v laboratornyh uslovijah. Moskva: Himija,1974. Izd. 4-e. 408 s. [in Russian].
11. Shiljaev B.A., Voevodin V.N. Istochniki postuplenija gelija i vodoroda v materialy vnutrikorpusnyh konstrukcij reaktorov s vodoj pod davleniem. Trudy XVII Mezhdunarodnoj konferencii po fizike radiacionnyh javlenij i radiacionnomu materialovedeniju, 4-9 sentjabrja 2006 g., Alushta, Krym. S. 185-186 [in Russian].
12. Baza znanij i nabor vychislitel'nyh algoritmov WolframAlpha. http:.www.wolframalpha.com/ [in Russian].
13. Gal'chineckij L.P. i dr. Vzaimodejstvie v sisteme ZnSe-ZnTe-Se-H2-C. Neorgan. materialy, 2005. T. 41, No. 9. S. 1065-1069 [in Russian].
14. Gal’chinetskii L.P. et al. Effect of Hydrogen on the Stability of Isovalently Doped ZnSe crystals. Inorganic Materials, Vol. 44, # 10, 2008, P. 1052-1056.
https://doi.org/10.1134/S002016850810004X
15. Kratkaja himicheskaja jenciklopedija. Red. I. L. Knunjanc i dr. Moskva: Sov. jencikl., 1961. T. 1. 1262 stb. [in Russian]
16. Galkin S.N. i dr. Izuchenie vzaimodejstvija komponentov v sisteme ZnSe-ZnTe-Se-H2. Zh. neorgan. himii. 1993. T. 38, No. 4. S. 711-713 [in Russian].
17. Zborshhik A.M. Teorija metallurgicheskih processov. Doneck: GVUZ «DonNTU», 2008. 101 s. http:.stee l times [in Russian]. ru/books/theory/theorymetalproc/theorymetalproc.php
18. Kratkaja himicheskaja jenciklopedija. Red. I.L. Knunjanc i dr. Moskva: Sov. jencikl., 1963. T. 2. 1088 stb. [in Russian].
19. Passivnyj kataliticheskij rekombinator vodoroda. Patent RF No. 2360734 [in Russian].